Chemistry - Chapman-Kolmogorov equation

In mathematics, specifically in probability theory, and yet more specifically in the theory of stochastic processes, the Chapman-Kolmogorov equation is an identity relating the joint probability distributions of different sets of coordinates on a stochastic process.

Suppose that { f_i } is an indexed collection of random variables, that is, a stochastic process. Let

$p_{i_1,\ldots,i_n}(f_1,\ldots,f_n)$

be the joint probability density function of the values of the random variables f₁ to f_n. Then, the Chapman-Kolmogorov equation is

$p_{i_1,\ldots,i_{n-1}}(f_1,\ldots,f_{n-1})=\int_{-\infty}^{\infty}p_{i_1,\ldots,i_n}(f_1,\ldots,f_n)\,df_n$

Particularization to Markov chains

When the stochastic process under consideration is Markovian, the Chapman-Kolmogorov equation is equivalent to an identity on transition densities. In the Markov chain setting, one assumes that $i_1<\ldots<i_n$ . Then, because of the Markov property,

$p_{i_1,\ldots,i_n}(f_1,\ldots,f_n)=p_{i_1}(f_1)p_{i_2;i_1}(f_2\mid f_1)\cdots p_{i_n;i_{n-1}}(f_n\mid f_{n-1}),$

where the conditional probability $p_{i;j}(f_i\mid f_j)$ is the transition probability between the times $i > j$ ). So, the Chapman-Kolmogorov equation takes the form

$p_{i_3;i_1}(f_3\mid f_1)=\int_{-\infty}^\infty p_{i_3;i_2}(f_3\mid f_2)p_{i_2;i_1}(f_2\mid f_1)df_2.$

When the probability distribution on the state space of a Markov chain is discrete, the Chapman-Kolmogorov equations can be expressed in terms of (possibly infinite-dimensional) matrix multiplication, thus:

P (t + s) = P (t) P (s)

where P(t) is the transition matrix, i.e., if X_t is the state of the process at time t, then for any two points i and j in the state space, we have

$P_{ij}(t)=P(X_t=j\mid X_0=i).$

External links

The Legacy of Andrei Nikolaevich Kolmogorov Curriculum Vitae and Biography. Kolmogorov School. Ph.D. students and descendants of A.N. Kolmogorov. A.N. Kolmogorov works, books, papers, articles. Photographs and Portraits of A.N. Kolmogorov.
Mathworld

Categories: Stochastic processes | Equations

Chapman-Kolmogorov equation

Particularization to Markov chains

See also

External links