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Eclipsed

In chemistry an eclipsed conformation is a chemical conformation that exists in any open chain single chemical bond connecting two sp3 hybridised atoms as a conformational energy maximum due to steric hindrance.



staggered conformation left, eclipsed conformation right

In the example of ethane in newman projection it shows that rotation around the carbon-carbon bond is not entirely free but that an energy barrier exists. The ethane molecule in the eclipsed conformation is said to suffer from torsional strain and by a rotation around the carbon carbon bond to the staggered conformation around 12.5 KJ/mole of torsional energy is released.

01-04-2007 01:16:19
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