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Propanal

Properties

General

Name Propanal
Chemical formula CH3CH2CHO
Formula weight 58.08 amu
Synonyms Propionaldehyde, methylacetaldehyde, propionic aldehyde, propaldehyde
CAS number 123-38-6
UN number 1275

Phase behavior

Melting point 192 K (-81°C)
Boiling point 321 K (48°C)
Triple point 171 K (-102°C)


? bar

Critical point  ?


? bar

ΔfusH 8.59 kJ/mol
ΔfusS  ? J/mol·K
ΔvapH 28.3 kJ/mol
Solubility 50-100 mg/ml

Liquid properties

ΔfH0liquid  ? kJ/mol
S0liquid  ? J/mol·K
Cp  ? J/mol·K
Density 0.81 ×103 kg/m3

Gas properties

ΔfH0gas  ? kJ/mol
S0gas J/mol·K
Cp  ? J/mol·K

Safety

Acute effects Respiratory irritation, dizziness, skin irritation.
Chronic effects Pulmonary oedema; mutagenic effects have been reported.
Flash point -26°C
Autoignition temperature 175°C
Explosive limits 2.3-21%

More info

Properties NIST WebBook
MSDS Hazardous Chemical Database

SI units were used where possible. Unless otherwise stated, standard conditions were used.

Disclaimer and references

In organic chemistry, propanal or propionaldehyde is the aldehyde of the 3 carbon propyl group. It has a chemical formula of CH3CH2CHO, and is a structural isomer of propanone. At room temperature, it is a colourless liquid with a slightly irritating, fruity odour.

Production

Propanal is mainly produced through the Fischer-Tropsch synthesis, combining synthesis gas (carbon monoxide and hydrogen) with ethene over a metal catalyst:

CO + H2 + C2H4 → CH3CH2CHO

Uses

It is principally used to make trimethylolethane through condensation with methanol; this process is important in the production of alkyd resins.

01-04-2007 01:16:19
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