Chemistry Reference and  Research
           
 
Periodic Table
- standard table
- large table
 
Chemical Elements
- by name
- by symbol
- by atomic number
 
Chemical Properties
 
Chemical Reactions
 
Organic Chemistry
 
Branches of Chemistry
Analytical chemistry
Biochemistry
Computational Chemistry
Electrochemistry
Environmental chemistry
Geochemistry
Inorganic chemistry
Materials science
Medicinal chemistry
Nuclear chemistry
Organic chemistry
Pharmacology
Physical chemistry
Polymer chemistry
Supramolecular Chemistry
Thermochemistry

Soman

Soman
Discovery
Discovered by Gerhard Schrader
Discovered in 1944
Chemical characteristics
Chemical name O-Pinacolyl methylphosphonofluoridate
Chemical family Fluorinated organophosphorus compound
Chemical formula C7H16F02P
NFPA Rating
  • Health - 4
  • Flammability - 1
  • Reactivity - 1
Boiling point 198 °C (388 °F)
Freezing/melting point -42 °C (-107.6 °F)
Vapor pressure 0.40 mmHg (53 Pa) at 25 °C
Vapor density (air=1) 6.3
Solubility in Water Moderate
Density at 25 °C 1.022 g/cm3
Appearance and color When pure, colorless liquid with fruity odor.
With impurities, amber or dark brown,
with oil of camphor odor

Soman or GD (O-Pinacolyl methylphosphonofluoridate) is an extrememly toxic substance that is one of the world's most dangerous weapons of war. Because it fatally interferes with normal functioning of the mammalian nervous system, it is classified as a nerve agent. As a chemical weapon, it is classified as a weapon of mass destruction by the United Nations according to UN Resolution 687, and its production and stockpiling was outlawed by the Chemical Weapons Convention of 1993. Soman was the third of the so-called G-series nerve agents discovered (along with GA (tabun), GB (sarin), and GF (cyclosarin)).

It is a volatile, corrosive and colourless liquid with a faint odour when pure, more commonly it is a yellow to brown color and has a stronger odour described as camphor. The LCt50 for Soman is 70 mg-min/m3 in humans. It is both more lethal and more persistent than sarin or tabun, but less than cyclosarin.

GD can be thickened for use as a chemical spray using an acryloid copolymer. It can also be deployed as a binary chemical weapon; its precursor chemicals are methylphosphonyl difluoride and a mixture of pinacolyl alcohol and an amine.

Alternative names

Soman is occasionally referred to names other than soman or GD:

  • Phosphonofluoridic acid, methyl-, 1, 2, 2-trimethylpropyl ester
  • Pinacolyl methylphosphonofluoridate
  • 1,2,2-Trimethylpropyl methylphosphonofluoridate
  • Methylpinacolyloxyfluorophosphine oxide
  • Pinacolyloxymethylphosphonyl flouride
  • Pinacolyl methanefluorophosphonate
  • Methylfluoropinacolylphosphonate
  • Fluoromethylpinacolyloxyphosphine Oxide
  • Methylpinacolyloxyphosphonyl flouride
  • Pinacolyl methylfluorophosphonate
  • 1,2,2,-Trimethylpropoxyfluoromethylphosphine oxide

History

Soman was discovered by Richard Kuhn in Germany in 1944, and represented the last wartime nerve agent discovery (GF was not found until 1949.) Soman was given the identifier GD post-war (GC was already in medical use) when the information relating to Soman was recovered by the Soviet Union from its hiding place in a mine.

References

01-04-2007 01:16:19
The contents of this article are licensed from Wikipedia.org under the GNU Free Documentation License. How to see transparent copy