Chemistry - Total angular momentum quantum number

The total angular quantum momentum numbers parameterize the total angular momentum of a given electron, by combining its orbital angular momentum and its intrinsic angular momentum (i.e., its spin).

If s is the electron spin angular momentum and l its orbital angular momentum vector, the total angular momentum j is

$\mathbf j = \mathbf s + \mathbf l$

The associated quantum number is the main total angular momentum quantum number j. It can take the following values:

$|l - s| \le j \le l + s$

where l is the azimuthal quantum number (parameterizing the orbital angular momentum) and s is the spin quantum number (parameterizing the spin).

The relation between the total angular momentum vector j and the total angular momentum quantum number j is given by the usual relation (see angular momentum quantum number)

$\Vert \mathbf j \Vert = \sqrt{j \, (j+1)} \, \hbar$

the vector's z-projection is given by

$j_z = m_j \, \hbar$

where m_j is the secondary total angular momentum quantum number. It ranges from −j to +j in steps of one. This generates 2j + 1 different values of m_j.

Total angular momentum quantum number

See also

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